6-Methoxy-4-methyl-2H-chromen-2-one

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7-(6-Bromo­hex­yloxy)-4-methyl-2H-chromen-2-one

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6-Meth­oxy-4-methyl-2H-chromen-2-one

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6-Chloro-4-(4-methyl­phen­oxy­meth­yl)-2H-chromen-2-one

In the title compound, C(17)H(13)ClO(3), the coumarin and phen-oxy moieties are essentially co-planar, making a dihedral angle of 1.99 (7)°. The phen-oxy moiety is oriented anti-periplanar with respect to the coumarin ring as indicated by the C-C-O-C angle of -179.97 (16)°. In the crystal, the sheet-like packing is stabilized by inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds.

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3,6,8-Tribromo-7-ethyl­amino-4-methyl-2H-chromen-2-one

In the title mol-ecule, C(12)H(10)Br(3)NO(2), the 2H-chromen ring is essentially planar (r.m.s. deviation = 0.022 Å) with the ethyl-amino group oriented at 13.9 (5)° with respect to the ring. The mol-ecular structure is stabilized by intra-molecular N-H⋯Br and C-H⋯Br interactions.

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3,6-Dibromo-7-ethyl­amino-4-methyl-2H-chromen-2-one

In title compound, C(12)H(11)Br(2)NO(2), the coumarin ring system is almost planar, the two rings being inclined to one another by 1.40 (15)°. There are two short intra-molecular inter-actions (N-H⋯Br and C-H⋯Br) involving the Br atoms. In the crystal, mol-ecules stack along the a-axis direction via π-π inter-actions; the centroid-centroid distances vary from 3.6484 (19) to 3.7942 (19) Å.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810051652